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The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32
Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   
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Dry valleys are a striking geographic landscape in Hengduan Mountains Region and are characterized by low rainfall, desert type of vegetation and fragile environment. Past efforts and resources have been concentrated mainly on rehabilitation of degraded ecosystem and fragile environment, particularly reforestation, while socio-economic development has been largely overlooked. Despite successes in pocket areas, the overall trend of unsustainability and environmental deterioration are continuing. It is important to understand that uplift of the Tibetan Plateau is the root cause of development of dry valleys, and development and formation of dry valleys is a natural process. Human intervention has played a secondary role in development of dry valleys and degradation of dry valleys though human intervention in many cases has speeded up environmental degradation of the dry valleys. It is important to understand that dry valleys are climatic enclaves and an integrated approach that combines rehabilitation of degraded ecosystems and socio-economic development should be adopted if the overall goal of sustainable development of dry valleys is to be achieved. Promotion of niche-based cash crops, rural energy including hydropower, solar energy, biogas and fuelwood plantation is recommended as the priority activities.  相似文献   
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